Carbon coated electric arc furnace dust prepared by one-pot pyrolysis: An efficient, low carbon footprint electrode material for lithium-ion batteries

Karahan B. D.

Materials Chemistry and Physics, vol.287, 2022 (SCI-Expanded) identifier identifier

  • Publication Type: Article / Article
  • Volume: 287
  • Publication Date: 2022
  • Doi Number: 10.1016/j.matchemphys.2022.126178
  • Journal Name: Materials Chemistry and Physics
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus, Academic Search Premier, Aerospace Database, Chemical Abstracts Core, Communication Abstracts, INSPEC, Metadex, Civil Engineering Abstracts
  • Keywords: Lithium-ion batteries, Carbon coating, Green electrode materials, Nanomaterials
  • Istanbul Medipol University Affiliated: Yes

Abstract

This work offers useful insights into the evaluation of the electric arc furnace dust in green energy applications by surface engineering. To produce low-carbon-footprint electrodes, for the first time in the open literature, the practical pyrolysis (of sucrose) method is applied to create a nanometer-thick carbon layer over the dust. Advanced techniques are used to characterize the carbon-coated electric arc furnace flue dust morphologically, structurally, and chemically. Galvanostatic tests reveal that the carbon-coated dust exhibits 600 mAh g−1 discharge capacity after 250 cycles. The rate test proves that the carbon-coated dust can withstand a high current load (2A g−1) and delivers 540 mAh g−1 after 250 cycles when the current load is decreased to 0.1A g−1. This obtained capacity shows that with the correct material selection and process design, it is possible to produce low-carbon footprint electrodes at a low cost. Electrochemical characterizations indicate that the lithiation reaction of the carbon-coated dust takes place similarly to that of the anode materials which are made of synthetically fabricated carbon-coated transition metal oxides and/or ferrites. It is anticipated that this study sets an example for the valorization of the various industrial wastes in energy applications in the future.